catena-Poly[[[bis(methylamine)zinc(II)]-μ-4,4′-oxydibenzoato] N,N-dimethylacetamide solvate]
نویسندگان
چکیده
In the title zinc(II) coordination polymer, {[Zn(C(14)H(8)O(5))(CH(5)N)(2)]·C(4)H(9)NO}(n), each Zn(II) cation is tetra-hedrally coordinated by two carboxyl-ato O atoms of two oba anions (H(2)oba is 4,4'-oxydibenzoic acid), and two N atoms from two methyl-amine mol-ecules. Each oba anion bridges two Zn(II) cations through the two carboxyl-ate groups in a monodentate fashion, forming one-dimensional polymeric chains. These chains are linked via N-H⋯O hydrogen bonds, forming a two-dimensional supra-molecular network.
منابع مشابه
Poly[zinc(II)-[μ-1,4-bis(imidazol-1-ylmethyl)benzene]-μ-4,4′-oxydibenzoato]
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متن کاملcatena-Poly[[[(2-phenylacetato-κO)zinc(II)]bis[μ-4,4′-(disulfanediyl)dipyridine-κ2 N:N′]] monohydrate]
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متن کاملBis(μ-2,2′-oxydibenzoato-κ4 O,O′:O′′,O′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc(II)] dihydrate
In the title compound, [Zn(2)(C(14)H(8)O(5))(2)(C(12)H(12)N(2))(2)]·2H(2)O, the Zn(II) atom exhibits a distorted octa-hedral coordination geometry, defined by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine ligand and four O atoms from two bridging 2,2'-oxydibenzoate ligands. The mol-ecule is a centrosymmetric dimer. π-π Stacking inter-actions are observed between the 4,4'-dimethyl-2,2'-bipy...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007